Piero Di Giuseppe studied Classical Guitar at the “Scuola di Musica di Fiesole” under the direction of Silvano Mazzoni and he obtained his diploma at the “Istituto Musicale Pareggiato “Pietro Mascagni” of Livorno.

Since 1999 he performs concert activity, both as a soloist and as a chamber musician. He has been a member of the "Fiesole Guitar Consort" since its foundation and he performed with them among others at "Salone dei 500" of Palazzo Vecchio in Florence.
In 2005 he performed Symphony No. 7 by Gustav Mahler, with the "Orchestra Giovanile Italiana" and the "Orchestra della Toscana", conducted by Gabriele Ferro in Pisa and Florence for the "ORT"'s XIV concert season.
He teaches music. Between 2005 and 2016 he taught at "Scuola Comunale di Musica D. Scarlatti" of Montale. Since 2005 he is a professor of Guitar at the “Scuola di Musica di Fiesole”